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Identifier

000378713

Title

Σύνθεση, δομή και ιδιότητες πολυλειτουργικών ανόργανων-οργανικών υβριδικών υλικών

Alternative Title

Synthesis, structure and properties of multifunctional metal-posphonate hybrid materials

Author

Αγγελή, Γιασεμή Κων.

Thesis advisor

Δημάδης, Κωνσταντίνος

Reviewer

Τρκαλίτης, Παντελής
Μήλιος, Κωνσταντίνος

Abstract

The emerging fields of supramolecular chemistry, crystal engineering, and materials chemistry have made long strides forward with impressive growth during the last decades. The chemistry of phosphonate ligands has undoubtedly played an important role in widening these areas of research. Phosphonate ligands have attracted considerable attention in the context of fundamental research, but they have also been extensively used in several other technologically/industrially significant areas, such as water treatment, oilfield drilling, minerals processing, corrosion control, metal complexation, etc. In this project we report the synthesis of two new families of metal phosphponate hybrid materials. The first group originates from the combination of the tetraphosphonic ligand BABBMP (1,4–bis(aminomethyl)benzene–N,N’– bis(methylenephosphonic acid)) with alkaline earth and transition metal ions, while the second group originates from the combination of the ligand AMP (aminotris(methylenephosphonic acid)) with lanthanide ions. All of these materials were characterized by physichochemical and structural methods, while the materials of the first group were studied for their anti-corrosive activity.

Language

Greek

Subject

Alcaline earths

Corrosion

Lanthanides

Posphonates

Αλκαλικές γαίες

Διάβρωση

Λανθανίδες

Φωσφονικά οξέα

Issue date