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Identifier

uch.chemistry.phd//1993DIS0166

Title

Μελέτη φωτοχημείας και χημικής κινητικής απλών νιτραμινών

Alternative Title

Study of photochemistry and chemical kinetics of simple nitramines

Author

Λαζάρου, Γιάννης Γ

Abstract

This thesis descrides the dissociation of the simple nitramines, dimethylnitramine and diethylnitramine through the irradiation with a pulse cardon dioxide laser. Irradiation leads to the scission of the weakest bond between nitrogen atoms in the molecule. The reactions that follow are mainly oxidation reactions of the dialkylaminyl radical produced primarily. The chemical reactivity of the methyl hydrogens of dimethylnitramine was studied with the "Very-low-pressure-reactor" technique by evaluating the mechanism and the kinetic parameters of the reaction of dimethylnitramine and chlorine atoms. Finally, the synthesis of molecules encountered in this thesis and application programs are presented.

Language

Greek

Issue date

1993-01-01

Date available

1997-06-6

Collection

School/Department--School of Sciences and Engineering--Department of Chemistry--Doctoral theses

Type of Work--Doctoral theses

Views

372

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