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Identifier

000316197

Title

Μελέτη του μηχανισμού της αντίδρασης της τριαζολινοδιόνης (RTAD) με αλκένια

Alternative Title

Mechanistic studies on the reaction of triazolinedione (RTAD) with alcanes

Author

Ρουμπελάκης, Εμμανουήλ Μιχαήλ

Thesis advisor

Ορφανόπουλος, Μιχαήλ

Abstract

In the present Thesis the vinylcyclopropyl moiety was used as an efficient probe to test mechanistic possibilities of the triazolinedione-alkene ene reaction. In nonhydroxylic solvents, this reaction afforded only the ene adducts via closed threemembered aziridinium imide (AI) intermediate, whereas in hydroxylic solvents a dipolar intermediate is favoured and trapped by the cyclopropyl moiety to form the corresponding cyclopropyl-rearranged solvent-trapped adducts

Physical description

xiii, 53 σ. : εικ. ; 30 εκ.

Language

Greek

Subject

aziridinium imide

cyclopropyl group

dipolar intermediate open

ene reaction

solvent-trapped adducts

triazolinediones

Πανεπιστήμιο Κρήτης. Διατριβές.