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Identifier uch.chemistry.phd//1993DIS0166
Title Μελέτη φωτοχημείας και χημικής κινητικής απλών νιτραμινών
Alternative Title Study of photochemistry and chemical kinetics of simple nitramines
Author Λαζάρου, Γιάννης Γ
Abstract This thesis descrides the dissociation of the simple nitramines, dimethylnitramine and diethylnitramine through the irradiation with a pulse cardon dioxide laser. Irradiation leads to the scission of the weakest bond between nitrogen atoms in the molecule. The reactions that follow are mainly oxidation reactions of the dialkylaminyl radical produced primarily. The chemical reactivity of the methyl hydrogens of dimethylnitramine was studied with the "Very-low-pressure-reactor" technique by evaluating the mechanism and the kinetic parameters of the reaction of dimethylnitramine and chlorine atoms. Finally, the synthesis of molecules encountered in this thesis and application programs are presented.
Language Greek
Issue date 1993-01-01
Date available 1997-06-6
Collection   School/Department--School of Sciences and Engineering--Department of Chemistry--Doctoral theses
  Type of Work--Doctoral theses
Permanent Link https://elocus.lib.uoc.gr//dlib/e/9/e/metadata-dlib-1993DIS0166.tkl Bookmark and Share
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