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Title Προσδιορισμός ανθρακούχων συστατικών (OC και EC) σε λεπτά αερολύματα στην Αθήνα σε περιοχή αστικού υπόβαθρου
Alternative Title Carbonaceous aerosols (OC and EC) at an urban background location in Athens
Author Μπάρδης, Γεώργιος
Thesis advisor Μιχαλόπουλος, Νικόλαος
Abstract The interest in the chemical composition of atmospheric particulate matter is significant, mainly due to their impacts on human health and climate change. The effects of particulate matter are important across all environmental sectors, particularly on health, which depends on the particle size, their chemical composition, and the presence of other pollutants with which they interact synergistically. The subject of this thesis is the study of the organic carbon (OC) and elemental carbon (EC) fractions of PM10 particles in the atmosphere of Athens during the year 2022 (January - December 2022). The samples were taken at the sampling station of the National Observatory of Athens, at the Thisseio facilities, and their analysis was conducted using a thermal/optical carbon analyzer for aerosols by Sunset Laboratory Inc. The results demonstrate a clear seasonal pattern, showing mostly peaks during the winter and minima in the summer months. The contribution of local sources increases during the winter period due to domestic heating and temperature inversions, while during the warm months, the concentrations are minimal due to low fuel consumption and reduced domestic heating. The ratio of organic to elemental carbon has an average value of 5.30±2.6, with maximum values during the warm months. The high ratio indicates the influence of secondary organic aerosol as values greater than 2 indicate twice the concentration of organic carbon compared to elemental carbon. Finally, these results were correlated with corresponding measurements from an aethalometer for the same period and area to determine the relationship of OC and EC with black carbon, which originates from fossil fuel combustion and biomass burning, to identify possible common sources. Considering the results of organic and elemental carbon from this study, we can conclude that the atmosphere of Thisseio in winter is burdened by fireplaces and biomass burning, as maximum concentrations of OC and EC are observed and the presence of secondary aerosols is evident.
Language Greek
Issue date 2024-07-19
Collection   School/Department--School of Sciences and Engineering--Department of Chemistry--Graduate theses
  Type of Work--Graduate theses
Permanent Link https://elocus.lib.uoc.gr//dlib/7/2/f/metadata-dlib-1720504602-542583-25235.tkl Bookmark and Share
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