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Identifier 000024174
Title Πορφυρινικά σύμπλοκα της σειράς των λανθανίδων με Π-Π αλληλεπιδράσεις. Σύνθεση και φασματοσκοπικός τους χαρακτηρισμός
Alternative Title Porphyrinic complexes with lanthanide series ions, exhibitimg π-π interactions. Synthesis and spectroscopic characterization
Author Σπυρούλιας, Γεώργιος Α
Thesis advisor Κουτσολέλος, Αθανάσιος
Abstract The above mentioned dissertation presents the synthesis of new Bis(porphyrinic) "Sandwich-like", complexes with Lanthanide ions. The complexes were characterized by various physicoche mical method as UV-visible, Infeared, EPR, NMR, Spectro scopies as well as Electrochemistry, Differaction with X-Rays and EXAFS Spectroscory. The main and interapting fealure of the complexes is the dependence of the vast majority of their physicochemical properrlies on the existence of a H+ in one of the eight nitragen atoms of one porpyrinic ring. The existeme of this H+ is soluent the H+ is abstracted from the complexes while in non basic solvent remains.
Language Greek
Subject Charge transfer bands
Electrochemistry of porhyrins
Lanthanides
Mono-, Bis-porphyrinates
Paramagnetic 1H-NMR
Porphyrin
Porphyrin sandwich complexes
Δι-πορφυρινικά σύμπλοκα
Ηλεκτροχημεία πορφυρίνων
Λανθανίδες
Μονο-πορφυρινικά σύμπλοκα
Παραμαγνητικό 1H-NMR
Πορφυρίνη
Πορφυρικά σύμπλοκα σάντουιτς
Ταινείες μεταφοράς φορτίου
π-π interactions
π-π αλληλεπιδράσεις
Issue date 1995-01-07
Collection   School/Department--School of Sciences and Engineering--Department of Chemistry--Doctoral theses
  Type of Work--Doctoral theses
Permanent Link https://elocus.lib.uoc.gr//dlib/b/7/1/metadata-dlib-1995DIS0173.tkl Bookmark and Share
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