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Identifier 000395189
Title Φωτοκαταλυομένες προσθήκες φθαλικών αλδεϋδών στο φουλερένιο C60
Alternative Title Photochemical additions of phthalaldehydes to fullerene C60
Author Μαλλιαρός, Νικήτας Γ
Thesis advisor Ορφανόπουλος, Μιχαήλ
Reviewer Στρατάκης, Εμμανουήλ
Βασιλικογιαννάκης, Γεώργιος
Abstract The present master thesis describes new photochemical reactions for the selective chemical modification of the fullerene C60 with isomeric phthalaldehydes, mediated by the polyoxometalate complex tetrabutylammonium decatungstate (n Bu4N)4W10O32 (TBADT). In this study, the additions via free acyl radicals of the ortho- isomer o-phthalaldehyde and the meta- isomer isophthalaldehyde were investigated. Over the course of the current research, the unexpected and interesting products which occurred were isolated and characterized. Finally, the deuterium intermolecular primary isotopic effect for the addition of isophthalaldehyde to C60 was determined. For this purpose, the deuterated compounds o-phthalaldehyde-d1 and isophthalaldehyde-d2 were prepared and well characterized.
Language Greek, English
Subject Photocatalytic additions
Φωτοχημικές προσθήκες
Issue date 2015-07-17
Collection   Faculty/Department--Faculty of Sciences and Engineering--Department of Chemistry--Post-graduate theses
  Type of Work--Post-graduate theses
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