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Identifier 000456882
Title 2D hybrid double halide perovskites and layered perovskites based on lead
Alternative Title 2D υβριδικοί διπλοί αλογονικοί περοβσκίτες και περοβσκίτες πολλαπλών στρώσεων
Author Μανιαδή, Μαρία
Thesis advisor Στούμπος, Κωνσταντίνος
Reviewer Κοπιδάκης, Γεώργιος
Αρματάς, Γεράσιμος
Abstract 2D halide perovskite semiconductors have shown a variety of applications in recent years, mainly in photovoltaics, attracting a plethora of scientists to this developing multidisciplinary field. The primary goal for this Thesis, is to further exploring the field, by synthesizing new 2D hybrid halide perovskites and trying to optimize certain aspects of the crystal and electronic band structure. Towards this end, the new organic diammonium spacer (2-halo, 1,3-diammino propane, DicX, X = Br, I) was introduced, in an attempt to examine the effect of the organic halide in the photophysical properties of the layered perovskites. The new spacer was employed towards the synthesis of the 2D homologous series (DicI)(CH3NH3) n-1 PbnI3n+1 (n = 1-3) as well as the synthesis of members of the corresponding 2D lead-free compounds based on ordered double perovskites combining Ag+ and Bi3+ double perovskites. As it was shown from optical measurements in the visible range, new compounds exhibit stable excitons at room temperature emitting in the wavelength range λ = 500-650nm consistent with their Multiple Quantum Well electronic structure. However, unlike other derivatives of the 2D perovskites, the binding energy of the materials appears to be significantly reduced, as a result of the organic spacer. The extra organ iodide in the spacer reduces the dielectric contrast between the organic and the inorganic components whereas the interlayer distance between the perovskite sheets is significantly reduced from the short carbon chain. As band structure calculations also support, the new materials effectively behave as bulk perovskites, resulting in a charge-transport in all three dimensions, a property that may have great impact in the application of these materials in solar cells. In an attempt to take advantage of this property, thin films of these layered 2D halide perovskites were fabricated and characterized. Future work on these materials will deal with the manufacture and characterization of full solar cells devices, where it is anticipated that we will be able to obtain a significant increase in the photo-generated current which may lead to an overall improved power-conversion efficiency.
Language English
Issue date 2023-07-19
Collection   School/Department--School of Sciences and Engineering--Department of Materials Science and Technology--Post-graduate theses
  Type of Work--Post-graduate theses
Permanent Link https://elocus.lib.uoc.gr//dlib/0/b/7/metadata-dlib-1688635547-794282-11199.tkl Bookmark and Share
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