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Identifier 000040093
Title Σύνθεση Πρόδρομων Πορφυρινικών Σκελετών Διμερών Πορφυρινών και Φασματοσκοπικός Χαρακτηρισμός τους
Author Γραμματικοπούλου, Μαρία
Thesis advisor Κουτσολέλος, Αθανάσιος
Abstract Porphyrins are involved in many biological or chemical processes in nature. Their applications are continuously growing and have extended to a great variety of biotechnological applications, necessarily resulting in more detailed study of their molecular properties and in more advanced approaches for their synthesis. The aim of the title work was the synthesis of a number of porphyrinic precursors, which were then to be used for the final synthesis of selected dimeric porphyrins clathrates. These aggregates can encapsulate molecules with specific molecular properties and dimensions into their internal cavity in order to be used as biomimic models for interpreting the role of certain metabolic enzymes. This property is rather exciting, since their applicable field can be extended and referred to processes where selective entrapment is needed, upon appropriate synthetic modification of their molecular structure and architecture. Finally, the conditions for combining the synthesized porphyrinic precursors in the presence of various coupling reactants, and the spectroscopic characterization of the ultimate products using Mass Spectrometry, UV-Vis, IR and NMR spectroscopies were the last goals of the present thesis.
Language Greek
Subject Clathrate
Co-facial
Dimer
Fullerenes
Meso-phenyl
Porphyrin
Precursors
Spectroscopy
Διμερή
Κλείθρο
Μεσο-φαίνυλο
Πορφυρίνη
Συνμετωπικά
Υποκαταστάτης
Φασματοσκοπία
Φουλλερένια
Issue date 2004-11-01
Collection   School/Department--School of Sciences and Engineering--Department of Chemistry--Post-graduate theses
  Type of Work--Post-graduate theses
Permanent Link https://elocus.lib.uoc.gr//dlib/5/7/6/metadata-dlib-2004grammatikopoulou.tkl Bookmark and Share
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